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Merck
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文件

17457

Sigma-Aldrich

α-溴异丁酸甲酯

≥99.0% (GC)

别名:

2-溴-2-甲基丙酸甲酯

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About This Item

线性分子式:
(CH3)2CBrCOOCH3
CAS号:
23426-63-3
分子量:
181.03
Beilstein:
1209484
EC號碼:
245-657-6
MDL號碼:
MFCD00017854
分類程式碼代碼:
12352100
PubChem物質ID:
57647652
NACRES:
NA.22

化驗

≥99.0% (GC)

形狀

liquid

密度

1.399 g/mL at 20 °C (lit.)

SMILES 字串

COC(=O)C(C)(C)Br

InChI

1S/C5H9BrO2/c1-5(2,6)4(7)8-3/h1-3H3

InChI 密鑰

PQUSVJVVRXWKDG-UHFFFAOYSA-N

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應用

可生成带有甲基末端基团的聚合物的原子转移自由基聚合 (ATRP) 引发剂
甲基 α-在 Reformatsky反应中使用了溴异丁酸盐，以制备 1,4-二取代 3,3-二甲基氮杂环丁烷-2-酮 。

象形圖

Flame
GHS02

訊號詞

Warning

危險聲明

H226

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

120.2 °F - closed cup

閃點（°C）

49 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Reformatsky reaction of methyl ?-bromoisobutyrate with Schiff bases derived from salicylaldehyde and 2-hydroxynaphthalene-1-carbaldehyde.
Russ. J. Org. Chem., 40(6), 834-836 (2004)

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