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Merck
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文件

163015

Sigma-Aldrich

硝酸铊(III) 三水合物

别名:

TTN, 三硝酸铊

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About This Item

线性分子式:
Tl(NO3)3 · 3H2O
CAS号:
13453-38-8
分子量:
444.44
EC號碼:
237-325-4
MDL號碼:
MFCD00149874
分類程式碼代碼:
12161600
PubChem物質ID:
24850018
NACRES:
NA.22

反應適用性

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES 字串

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI 密鑰

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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應用

本试剂可用于将苯乙烯衍生物快速氧化成羰基化合物，用于通过氧化重排进行环芳烷基酮的区域选择性扩环反应，用于硫缩醛到羰基化合物的选择性水解以及用于 19-降甾族化合物的一般合成方法。介导环酮的缩环反应，生成一系列反式稠合的 10-甲基-2-萘烷酮。

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Tetrahedron Letters, 1827-1827 (1977)
Lamis Yehia et al.
NPJ genomic medicine, 2, 37-37 (2017-12-22)
Bannayan-Riley-Ruvalcaba syndrome (BRRS) is a rare congenital disorder classically characterized by macrocephaly in combination with intestinal hamartomatous polyposis, vascular malformations, lipomas, and genital lentiginosis. Germline
Marta Gigli et al.
Journal of the American College of Cardiology, 74(11), 1480-1490 (2019-09-14)
Genotype-phenotype correlations in dilated cardiomyopathy (DCM) and, in particular, the effects of gene variants on clinical outcomes remain poorly understood. The purpose of this study was to investigate the prognostic role of genetic variant carrier status in a large cohort
Kevin Yauy et al.
The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations
Enrico Bugiardini et al.
Frontiers in neurology, 9, 456-456 (2018-07-13)
Objective: Distal myopathies are a diagnostically challenging group of diseases. We wanted to understand the value of MRI in the current clinical setting and explore the potential for optimizing its clinical application. Methods: We retrospectively audited the diagnostic workup in
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