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Merck

161241

Sigma-Aldrich

1-苯基-1-丙炔

99%

别名:

1-丙烯基苯, 1-炔丙基-1-苯, 1-甲基-2-苯乙炔, 3-苯基-2-丙炔, 甲基苯乙炔, 苯基甲基乙炔, (2-甲基乙炔基)苯

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About This Item

线性分子式:
C6H5C≡CCH3
CAS号:
分子量:
116.16
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.564 (lit.)

bp

185 °C (lit.)

密度

0.928 g/mL at 25 °C (lit.)

官能基

phenyl

儲存溫度

2-8°C

SMILES 字串

CC#Cc1ccccc1

InChI

1S/C9H8/c1-2-6-9-7-4-3-5-8-9/h3-5,7-8H,1H3

InChI 密鑰

GHUURDQYRGVEHX-UHFFFAOYSA-N

一般說明

研究人员已经报道过环戊烯和1-苯基-1-丙炔的共催化反应。研究人员采用程序升温脱附(temperature-programmed desorption)、X射线和双光子发射光谱研究了100K 下铜(111)上1-苯基-1-丙炔的成键性质。1-苯基-1-丙炔是多巴胺-β羟化酶的抑制剂。研究人员已经报道过通过TaCl5和 NbCl5进行1-苯基-1-丙炔的聚合。

1-苯基-1-丙炔可作为各种化学反应的原料,如加成反应和聚合。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

143.6 °F - closed cup

閃點(°C)

62 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

Lot/Batch Number

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Youngku Sohn et al.
Langmuir : the ACS journal of surfaces and colloids, 23(24), 12185-12191 (2007-10-31)
The bonding properties of 1-phenyl-1-propyne (PP, C6H5CCCH3) on Cu(111) at 100 K have been studied using temperature-programmed desorption (TPD), and X-ray, ultraviolet, and two-photon photoemission spectroscopies (XPS, UPS, and 2PPE). In TPD, there is no evidence for dissociation. Multilayer desorption
Effect of organometallic cocatalysts on the polymerization of 1-phenyl-1-propyne by tantalum pentachloride (TaCl5) and niobium pentachloride (NbCl5).
Masuda T, et al.
Macromolecules, 18(11), 2109-2113 (1985)
Shuhuai Xiang et al.
Journal of the American Chemical Society, 136(16), 5832-5835 (2014-04-12)
Here we report a general method for the measurement of (13)C kinetic isotope effects at natural abundance for reactions that yield two or more products concurrently. We use, as an example, a recently reported Co-catalyzed reaction between cyclopentene and 1-phenyl-1-propyne.
Ekaterina V Pokochueva et al.
Physical chemistry chemical physics : PCCP, 21(48), 26477-26482 (2019-11-30)
Parahydrogen-induced polarization (PHIP) is a powerful technique for studying hydrogenation reactions in gas and liquid phases. Pairwise addition of parahydrogen to the hydrogenation substrate imparts nuclear spin order to reaction products, manifested as enhanced 1H NMR signals from the nascent
G Colombo et al.
The Journal of biological chemistry, 259(24), 15017-15020 (1984-12-25)
The catalytic action of dopamine beta-hydroxylase on 1-phenyl-1-propyne results in concomitant loss of enzyme activity. At pH 5.5 and 25 degrees C, 1-phenyl-1-propyne inactivates dopamine beta-hydroxylase in a mechanism-based fashion. The inactivation rate is first-order, follows saturation kinetics, and is

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