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化驗
98%
形狀
liquid
折射率
n20/D 1.487 (lit.)
bp
181 °C (lit.)
密度
1.179 g/mL at 25 °C (lit.)
官能基
ester
SMILES 字串
COC(=O)c1ccco1
InChI
1S/C6H6O3/c1-8-6(7)5-3-2-4-9-5/h2-4H,1H3
InChI 密鑰
HDJLSECJEQSPKW-UHFFFAOYSA-N
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應用
2-糠酸甲酯(呋喃-2-羧酸甲酯,焦木酸甲酯)被用于合成顺式融合的5-氧呋喃[2,3-b]呋喃。它也可用于倍半萜内酯的制备。
訊號詞
Danger
危險分類
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
163.4 °F - closed cup
閃點(°C)
73 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Andreas Kreuzer et al.
Organic letters, 15(13), 3420-3423 (2013-06-26)
The first total synthesis of either enantiomer of Arteludovicinolide A and their biological evaluation is reported, featuring a new strategy for the asymmetric construction of γ-butyrolactones with stereogenic side chains in the 4-position. Starting from the renewable resource methyl 2-furoate
Roland Weisser et al.
Organic letters, 7(24), 5353-5356 (2005-11-18)
[structure: see text] A short and enantioselective synthesis of cis-fused 5-oxofuro[2,3-b]furans, being found in many spongiane diterpenoid natural products, is reported starting from inexpensive methyl 2-furoate. Moreover, the acid-catalyzed rearrangement of the furo[2,3-b]furan framework A to B is observed for
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