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品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.443 (lit.)
bp
92 °C (lit.)
mp
−34 °C (lit.)
密度
1.158 g/mL at 25 °C (lit.)
官能基
fluoro
SMILES 字串
Fc1ccccc1F
InChI
1S/C6H4F2/c7-5-3-1-2-4-6(5)8/h1-4H
InChI 密鑰
GOYDNIKZWGIXJT-UHFFFAOYSA-N
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一般說明
1,2-二氟苯在 NaOAc 存在下与铑吡啶膦和联吡啶配合物(固定在二氧化硅负载的钯催化剂上)在非常温和的条件下通过 H 2 发生脱氟反应 。
應用
1,2-二氟苯 (1,2-DFB) 被用于研究邻-、间-和对-二氟苯离子的离解机制。它和 x 射线光电子能谱和程序升温脱附一起用来研究 1,2-DFB、1,2-二氯苯和 1,2-二溴苯在 Si (100) 2 x 1 上的室温吸附。。它还被用作转换金属配合物电化学研究的溶剂 。
用于过渡金属络合物的电化学研究的溶剂。
其他客户在看
Hydrodefluorination of fluorobenzene and 1, 2-difluorobenzene under mild conditions over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst.
Organometallics, 18(12), 2285-2287 (1999)
Competition between associative and dissociative adsorption of 1, 2-dihalogenated benzenes on Si (100) 2? 1: Formation of dihalocyclohexadiene, halophenyl and phenylene adstructures.
Surface Science, 600(16), 3285-3296 (2006)
Journal of the American Society for Mass Spectrometry, 20(1), 20-24 (2008-10-18)
Threshold photoelectron photoion coincidence (TPEPICO) experiments have shown that o-, m-, and p-difluorobenzene ions dissociate via a common, ring-opened intermediate and not via ionized p-difluorobenzene. Rice-Ramsperger-Kassel-Marcus (RRKM) modeling of the experimental breakdown curves yields activation energies for the initial isomerization
Inorganic Chemistry, 28, 3923-3923 (1989)
Chemosphere, 186, 151-159 (2017-08-05)
Electronic noses have been widely used in the food industry to monitor process performance and quality control, but use in wastewater and biosolids treatment has not been fully explored. Therefore, we examined the feasibility of an electronic nose to discriminate
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