124087

2-溴-4-甲基苯胺

98%

• 别名: 2-溴-对甲苯胺, 4-氨基-3-溴甲苯
• 线性分子式: BrC₆H₃(CH₃)NH₂
• CAS号: 583-68-6
• 分子量: 186.05
• Beilstein: 1931711
• EC號碼: 209-515-7
• MDL號碼: MFCD00007635
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24847595
• NACRES: NA.22

属性

• 化驗: 98%
• 形狀: liquid
• 折射率: n20/D 1.602 (lit.)
• bp: 240 °C (lit.)
• mp: 14-16 °C (lit.)
• 密度: 1.5 g/mL at 25 °C (lit.)
• 官能基: bromo
• SMILES 字串: Cc1ccc(N)c(Br)c1
• InChI: 1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
• InChI 密鑰: UVRRJILIXQAAFK-UHFFFAOYSA-N

说明

一般說明

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me₃Al to form amide.

應用

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.

安全信息

• 象形圖: GHS06
• 訊號詞: Danger
• 危險聲明: H301 + H311 + H331
• 防範說明: P261 - P264 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• 危險分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 230.0 °F - closed cup
• 閃點（°C）: 110 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter