19170
3-Buten-1-ol
purum, ≥98.0% (GC)
Synonym(s):
Allylcarbinol
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About This Item
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grade
purum
Quality Level
Assay
≥98.0% (GC)
refractive index
n20/D 1.421 (lit.)
n20/D 1.422
bp
112-114 °C (lit.)
density
0.838 g/mL at 25 °C (lit.)
functional group
allyl
hydroxyl
SMILES string
OCCC=C
InChI
1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2
InChI key
ZSPTYLOMNJNZNG-UHFFFAOYSA-N
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Application
3-Buten-1-ol was used as a starting reagent in asymmetric total synthesis of natural seimatopolide B. It was also used in the synthesis of catalytic bimetallic nanoparticles.
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
91.4 °F - closed cup
Flash Point(C)
33 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Organic & biomolecular chemistry, 11(20), 3355-3364 (2013-04-09)
The asymmetric total synthesis of natural seimatopolide B along with its enantiomer is described starting from readily available 5-hexen-1-ol and 3-buten-1-ol. The key steps involved are Jacobson hydrolytic kinetic resolution, proline-catalyzed α-hydroxylation, Yamaguchi esterification and ring-closing metathesis. This asymmetric total
Alternating copolymers of functional alkenes with carbon monoxide.
Macromolecules, 29(18), 5852-5858 (1996)
Biologically programmed synthesis of bimetallic nanostructures.
Advanced Materials, 18(15), 1988-1992 (2006)
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