905291

Rh₂(R-BTPCP)₄

• Synonyme(s) : Davies dirhodium catalyst, Dirhodium tetrakis((S,R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate), Dirhodium tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylate], Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II), Tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylato]dirhodium(II)
• Formule empirique (notation de Hill): C₈₈H₆₄Br₄O₈Rh₂
• Numéro CAS: 1345974-62-0
• Poids moléculaire : 1774.87
• Code UNSPSC : 12161600
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder or crystals
• Pf: >300 °C

Description

Application

Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H funcionalization under low catalyst loadings.

Autres remarques

D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application

Enantioselective Synthesis of 2-Arylbicyclo[1.1.0]butane Carboxylates

Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable