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642452

Sigma-Aldrich

Molybdenum(V) chloride

anhydrous, powder, 99.99% trace metals basis (excluding W)

Synonyme(s) :

Molybdenum pentachloride, Molybdenum(5+) chloride

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About This Item

Formule linéaire :
MoCl5
Numéro CAS:
10241-05-1
Poids moléculaire :
273.21
Numéro CE :
233-575-3
Numéro MDL:
MFCD00003467
Code UNSPSC :
12352302
ID de substance PubChem :
24883197
Nomenclature NACRES :
NA.23

Qualité

anhydrous

Pression de vapeur

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

Essai

99.99% trace metals basis (excluding W)

Forme

powder

Impuretés

≤150.0 ppm Trace Metal Analysis

pb

268 °C (lit.)

Pf

194 °C (lit.)

Densité

2.928 g/mL at 25 °C (lit.)

Application(s)

battery manufacturing

Chaîne SMILES 

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

Clé InChI

GICWIDZXWJGTCI-UHFFFAOYSA-I

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Description générale

Molybdenum(V) chloride, also called as molybdenum pentachloride is a Lewis acid with high oxidation potential. It is widely used as a catalyst in the field of organic synthesis and polymer chemistry. It is also used as a chemical vapor deposition precursor.

Application

Molybdenum(V) chloride can be used:
  • As a catalyst for amidation of secondary benzyl alcohols.
  • As a precursor to fabricate MoS2 thin films by atomic layer deposition method.
  • As a primary catalyst for coordination polymerization of butadiene.
  • To fabricate superior anode materials for Na-ion and Li-ion batteries.
  • As a dual-function redox mediator for Li–O2 batteries to overcome thehigh polarization and low energy density issues.

À utiliser avec

Réf. du produit
Description
Tarif

Pictogrammes

Corrosion
GHS05

Mention d'avertissement

Danger

Mentions de danger

H314

Classification des risques

Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
MKCB6440
MKBT1696V
MKBW6749V
MKBT1392V
MKBS0899V

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Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular

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