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394912

Supelco

Heptafluorobutyric anhydride

for GC derivatization, LiChropur™, ≥99.0%

Synonyme(s) :

HFBA

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About This Item

Formule linéaire :
(CF3CF2CF2CO)2O
Numéro CAS:
336-59-4
Poids moléculaire :
410.06
Numéro Beilstein :
856036
Numéro CE :
206-410-8
Numéro MDL:
MFCD00000432
Code UNSPSC :
12000000
ID de substance PubChem :
24864629
Nomenclature NACRES :
NA.22

Qualité

for GC derivatization
LiChropur™

Pureté

≥99.0%

Forme

liquid

Pertinence de la réaction

reagent type: derivatization reagent
reaction type: Acylations

Technique(s)

gas chromatography (GC): suitable

Indice de réfraction

n20/D 1.287 (lit.)

Point d'ébullition

108-110 °C (lit.)

Pf

−43 °C (lit.)

Densité

1.674 g/mL at 20 °C (lit.)

Chaîne SMILES 

FC(F)(F)C(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22

Clé InChI

UFFSXJKVKBQEHC-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Heptafluorobutyric anhydride (HFB) is a derivatizing reagent. It provides facile and sensitive way for detecting and elucidating structure of numerous alkyl-chain homologs.

Application

Learn more in the Product Information
GC derivatizing agent used to prepare volatile derivatives of amino acids and other biologically active compounds.
HFB was used as derivatizing agent in analysing platelet-activating factor using GC-MS.
Suitable for the derivatization of aldosterone, digoxin, digitoxin and metabolites, estradiol, postaglandins F1α and F2α, 3-oxo-Δ4-steroids, and testosterone.

Conditionnement

Derivatization reagent used in a GC-MS analysis of stereoisomer content of synthetic peptides.

Autres remarques

Reagent for heptafluorobutyrate, 3-enol heptafluorobutyrate, 17-heptafluorobutyrate, heptafluorobutyrate and heptafluorobutyryl.

Informations légales

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

À utiliser avec

Réf. du produit
Description
Tarif

Pictogrammes

Corrosion
GHS05

Mention d'avertissement

Danger

Mentions de danger

H314

Classification des risques

Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
MKCL0438
MKCB2807V
MKBZ9763V
MKBZ0100V
MKBV1684V

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

S T Weintraub et al.
Journal of lipid research, 31(4), 719-725 (1990-04-01)
Parallel analysis of platelet-activating factor (PAF) using chemical ionization gas chromatography-mass spectrometry after direct derivatization with pentafluorobenzoyl chloride (PFB) and heptafluorobutyric anhydride (HFB) provides a facile and highly sensitive means for detecting and elucidating the structure of the numerous alkyl-chain
J Bakthavachalam et al.
Journal of chromatography, 500, 373-386 (1990-02-02)
Several electrophoric derivatives of 1-aminopyrene and 2-aminofluorene were prepared. Reagents such as heptafluorobutyryl chloride, pentafluorobenzoyl chloride, pentafluorobenzyl bromide and pentafluorobenzaldehyde, alone and in certain combinations, were employed. The ease of formation, yield, stability and fragmentation by gas chromatography with electron-capture
Ralf Pätzold et al.
Chirality, 18(7), 551-557 (2006-05-10)
Synthetic dipeptides comprising mixtures of enantiomers, diastereomers, or sequential isomers were converted into their N-perfluoroacetyl dipeptide esters (perfluoroacetyl: trifluoroacetyl, pentafluoroacetyl, heptafluorobutyryl; ester: methyl, 1-propyl, 2-propyl, 2,2,2-trifluoroethyl) and analyzed by GC-MS on the chiral stationary phases Chirasil-L-Val and Lipodex-E using helium
C Fakt et al.
Journal of chromatography. B, Biomedical sciences and applications, 700(1-2), 93-100 (1997-12-09)
A convenient and sensitive method for the quantitative determination of poly(ethylene glycol) 400 in plasma and urine with capillary gas chromatography-mass spectrometry has been developed. The sample preparation involves solid-phase extraction with subsequent derivatization with heptafluorobutyric anhydride, which proved to
Oliver Lerch et al.
Journal of chromatography. A, 991(1), 77-97 (2003-04-22)
Methods for ultra trace detection of endocrine disruptive chemicals (EDCs) are needed because of their low levels of impact. Twenty-one EDCs were selected, including 17beta-estradiol, 17alpha-ethinylestradiol, 17beta-testosterone and bisphenol A. Derivatisation with eight different fluorine containing compounds was examined. All
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