391638

Dimethylphosphoramidous dichloride

97%

• Synonyme(s) : (Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride
• Formule linéaire : (CH₃)₂NPCl₂
• Numéro CAS: 683-85-2
• Poids moléculaire : 145.96
• Numéro MDL: MFCD00013613
• Code UNSPSC : 12352100
• ID de substance PubChem : 24864392
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Pureté: 97%
• Forme: liquid
• Indice de réfraction: n20/D 1.505 (lit.)
• Point d'ébullition: 150 °C (lit.)
• Densité: 1.271 g/mL at 25 °C (lit.)
• Groupe fonctionnel: amine
• Température de stockage: 2-8°C
• Chaîne SMILES: CN(C)P(Cl)Cl
• InChI: 1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
• Clé InChI: XPWWDZRSNFSLRQ-UHFFFAOYSA-N

Description

Description générale

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C₁ symmetry and anti-conformer with C_s symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the ³⁵Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO₂ has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

Application

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:

• N,N-dimethylamidotetrachlorophosphorane
• O-propylchloroformimino-N,N-dimethylamidochlorophosphate
• 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H225,H314
• Conseils de prudence: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Risques supp: EUH014
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): -9.4 °F - closed cup
• Point d'éclair (°C): -23 °C - closed cup
• Équipement de protection individuelle: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter