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T5783

Supelco

2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate

for chiral derivatization, LiChropur™, ≥98.0% (HPLC)

Sinónimos:

GITC

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About This Item

Fórmula empírica (notación de Hill):
C15H19NO9S
Número de CAS:
14152-97-7
Peso molecular:
389.38
Beilstein:
56699
Número MDL:
MFCD00043085
Código UNSPSC:
12000000
ID de la sustancia en PubChem:
24900314
NACRES:
NA.22

grado

for chiral derivatization

Análisis

≥98.0% (HPLC)

calidad

LiChropur™

técnicas

HPLC: suitable

mp

114-116 °C (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

CC(=O)OC[C@H]1O[C@@H](N=C=S)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

InChI

1S/C15H19NO9S/c1-7(17)21-5-11-12(22-8(2)18)13(23-9(3)19)14(24-10(4)20)15(25-11)16-6-26/h11-15H,5H2,1-4H3/t11-,12-,13+,14-,15-/m1/s1

Clave InChI

WOWNQYXIQWQJRJ-UXXRCYHCSA-N

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Descripción general

2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate is a chiral derivatization reagent which reacts mainly with enantiomeric amino acids.

Aplicación

Chiral reagent for resolution of amino acid derivatives.
GITC may have been used in the formation of diastereomers and for reversed-phase high-performance liquid chromatographic resolution of amino acid enantiomers.

Envase

Bottomless glass bottle. Contents are inside inserted fused cone.

Productos recomendados

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Información legal

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Health hazardExclamation mark
GHS08,GHS07

Palabra de señalización

Danger

Frases de peligro

H315,H317,H319,H334,H335

Clasificaciones de peligro

Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

225649

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Zhiqiong Chen et al.
Journal of separation science, 28(2), 193-196 (2005-03-10)
Chiral separation of racemic mixtures is of the greatest importance to the pharmaceutical industry, as the isomers of a given racemate may exhibit substantially different pharmacological effects, not to mention possibly differing toxicity behaviour. A novel chiral separation method is
J Gal et al.
Journal of pharmacological methods, 16(3), 261-269 (1986-11-01)
Many established and experimental adrenergic agonists are derivatives of 2-aminoethanol with a phenol or catechol moiety in the 1-position. There is considerable interest in the stereochemical aspects of the actions of such chiral drugs. Surprisingly, however, little has been published
X Li et al.
Journal of chromatography. B, Biomedical sciences and applications, 742(2), 433-439 (2000-07-20)
A reversed-phase high-performance liquid chromatographic method for the determination of the enantiomers of atenolol in rat hepatic microsome has been developed. Racemic atenolol was extracted from alkalinized rat hepatic microsome by ethyl acetate. The organic layer was dried with anhydrous
Sherry Wang et al.
Journal of pharmaceutical and biomedical analysis, 43(2), 701-707 (2006-09-09)
A stable isotopically labeled (SIL) analogue is believed to be the most appropriate internal standard in a quantitative bioanalytical liquid chromatography/tandem mass spectrometry (LC/MS/MS) assay. It is assumed that a SIL internal standard always compensates for variability in chemical derivatization
Klaas E A Max et al.
Proceedings of the National Academy of Sciences of the United States of America, 115(23), E5334-E5343 (2018-05-20)
Circulating extracellular RNAs (exRNAs) have the potential to serve as biomarkers for a wide range of medical conditions. However, limitations in existing exRNA isolation methods and a lack of knowledge on parameters affecting exRNA variability in human samples may hinder
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Protocolos

Enantiomeric Purities of Pharmaceuticals Using Carbohydrate-based Isothiocyanates

Enantiomeric analysis of neurotransmitters and pharmaceuticals carrying functional amino groups, ß-adrenergic blockers; penicillamine, mexiletine; fine chemicals such as 1-phenyl-2-aminoethanol.

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