155810

2-Methyltetrahydrofuran

BioRenewable, ReagentPlus^®, ≥99.5%, contains 150-400 ppm BHT as stabilizer

• Sinónimos: 2-MeTHF, Tetrahydro-2-methylfuran, Tetrahydrosilvan
• Fórmula empírica (notación de Hill): C₅H₁₀O
• Número de CAS: 96-47-9
• Peso molecular: 86.13
• Beilstein: 102448
• Número CE: 202-507-4
• Número MDL: MFCD00005367
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 329750937
• NACRES: NA.21

Propiedades

• Nivel de calidad: 100
• Línea del producto: ReagentPlus^®
• Análisis: ≥99.5%
• formulario: liquid
• contiene: 150-400 ppm BHT as stabilizer
• lim. expl.: 0.34-6.3 %
• características de los productos alternativos más sostenibles: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• impurezas: ≤1.0% water (coulometr.); ≤100 ppm peroxide (as H₂O₂)
• índice de refracción: n20/D 1.406 (lit.)
• bp: 78-80 °C (lit.)
• mp: -136 °C
• densidad: 0.86 g/mL at 25 °C (lit.)
• categoría alternativa más sostenible: Aligned,
• cadena SMILES: CC1CCCO1
• InChI: 1S/C5H10O/c1-5-3-2-4-6-5/h5H,2-4H2,1H3
• Clave InChI: JWUJQDFVADABEY-UHFFFAOYSA-N

Descripción

Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is biorenewable and thus it aligns with "Safer Solvents and Auxiliaries" and "Use of Renewable Feedstocks".  Click here  for more information.

2-Methyltetrahydrofuran (2-MTHF), a 2-methyl substituted tetrahydrofuran, is a biomass derived, environmentally favorable solvent alternative to tetrahydrofuran (THF), 1,4 Dioxane (Dioxane) and dichloromethane (DCM) for most industrial applications. Its polarity and Lewis base strength is intermediate between tetrahydrofuran (THF) and diethyl ether. It is a potential greener solvent alternative for organic synthesis and shows resistance to reduction by lithium making it a promising candidate as electrolytes in lithium batteries.

Aplicación

2-Methyltetrahydrofuran may be used as an alternative solvent to:
THF in organometallic reactions

• Grignard
• Reformantsky
• Lithiation
• Hydride Reduction
• Metal-Catalyzed Coupling (Heck, Stile, Suzuki)

Dichloromethane for Biphasic Reactions:

• Alkylation
• Amidation
• Nucleophilic Substitution

Características y beneficios

• Made from Renewable Resource - furfural derived from agricultural byproducts
• High boiling point
• Clean organic-water phase separation
• Reduced energy to recover
  

Otras notas

To see other BioRenewable or Greener Solvents

Información legal

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• Pictogramas: GHS02,GHS05,GHS07
• Palabra de señalización: Danger
• Frases de peligro: H225,H302,H315,H318
• Consejos de prudencia: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2
• Riesgos supl.: EUH019
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 2
• Punto de inflamabilidad (°F): 14.0 °F - closed cup
• Punto de inflamabilidad (°C): -10.0 °C - closed cup