87920
Tetramethylsilane
analytical standard, for NMR spectroscopy, ACS reagent
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About This Item
Fórmula lineal:
Si(CH3)4
Número de CAS:
Peso molecular:
88.22
Beilstein:
1696908
Número CE:
Número MDL:
Código UNSPSC:
12142201
ID de la sustancia en PubChem:
NACRES:
NA.24
Productos recomendados
grado
ACS reagent
analytical standard
for NMR spectroscopy
Nivel de calidad
presión de vapor
11.66 psi ( 20 °C)
Análisis
≥99.5% (GC)
formulario
liquid
temp. de autoignición
842 °F
índice de refracción
n20/D 1.358 (lit.)
n20/D 1.359
bp
26-28 °C (lit.)
mp
−99 °C (lit.)
densidad
0.648 g/mL at 25 °C (lit.)
aplicaciones
environmental
formato
neat
temp. de almacenamiento
2-8°C
cadena SMILES
C[Si](C)(C)C
InChI
1S/C4H12Si/c1-5(2,3)4/h1-4H3
Clave InChI
CZDYPVPMEAXLPK-UHFFFAOYSA-N
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Descripción general
Tetramethylsilane has been recommended by the International Union of Pure and Applied Chemistry (IUPAC) as a universal reference for all nuclides. It is commonly used as a reference standard in nuclear magnetic resonance (NMR) for measuring proton chemical shifts and the temperature dependence of the 1H chemical shift of TMS in solvents such as chloroform, methanol, and dimethylsulfoxide is studied.
Aplicación
Tetramethylsilane may be used as an internal standard for the quantitative analysis of medicinal plant extracts and herbal products using the quantitative NMR (qNMR) method. It may also be used as an internal standard to investigate peroxide-based chemical systems for the crosslinking reactions carried on isotactic polypropylene using FT-IR spectrometry and proton nuclear magnetic resonance (1H NMR) techniques.
Palabra de señalización
Danger
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Flam. Liq. 1
Código de clase de almacenamiento
3 - Flammable liquids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
-16.6 °F - closed cup
Punto de inflamabilidad (°C)
-27 °C - closed cup
Equipo de protección personal
Eyeshields, Faceshields, Gloves
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Los clientes también vieron
Ramesh C Sharma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 65(3-4), 787-791 (2006-03-15)
The decomposition of trimethylsilane and tetramethylsilane has been investigated for the first time, using hot wire (catalytic) at various temperatures. Trimethylsilane is catalytic-dissociated in these species SiH(2), CH(3)SiH, CH(3), CH(2)Si. Time of flight mass spectroscopy signal of these species are
K Eberle et al.
Physics in medicine and biology, 48(21), 3555-3564 (2003-12-05)
First measurements with a prototype ionization chamber are described to be applied in online monitoring of modulated fields in radiation therapy. The liquids isooctane, isononane (TMP) and tetramethylsilane (TMS) are used in a high purity grade in order to realize
Robin K Harris et al.
Magnetic resonance in chemistry : MRC, 45 Suppl 1, S174-S186 (2007-12-25)
Computations for chemical shifts of molecular organic compounds using the gauge-including projector augmented wave method and the NMR-CASTEP code are reviewed. The methods are briefly introduced, and some general aspects involving the sources of uncertainty in the results are explored.
Roy E Hoffman
Journal of magnetic resonance (San Diego, Calif. : 1997), 163(2), 325-331 (2003-08-14)
The chemical shift of TMS is commonly assumed to be zero. However, it varies by over 1 ppm for 1H and 4 ppm for 13C and shows a correlation with the physical properties of the solvent. Using the commonly accepted
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