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Merck

439223

Sigma-Aldrich

Diclorometano

suitable for HPLC, ≥99.9%, contains 40-150 ppm amylene as stabilizer

Sinónimos:

Cloruro de metileno

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About This Item

Fórmula empírica (notación de Hill):
CH2Cl2
Número de CAS:
Peso molecular:
84.93
Beilstein:
1730800
Número CE:
Número MDL:
Código UNSPSC:
12190000
ID de la sustancia en PubChem:
NACRES:
NA.21

densidad de vapor

2.9 (vs air)

Nivel de calidad

presión de vapor

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

Análisis

≥99.9%

formulario

liquid

temp. de autoignición

1223 °F

contiene

40-150 ppm amylene as stabilizer

lim. expl.

22 %

técnicas

HPLC: suitable

impurezas

Free halogens, passes test
≤0.0003 meq/g Titr. acid
≤0.02% water

residuo de evap.

<0.0003%

color

APHA: ≤10
clear

índice de refracción

n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

densidad

1.325 g/mL at 25 °C (lit.)

λ

H2O reference

Absorción UV

λ: 235 nm Amax: 1.00
λ: 240 nm Amax: 0.20
λ: 250 nm Amax: 0.05
λ: 260 nm Amax: 0.02
λ: 340-400 nm Amax: 0.01

idoneidad

passes test for HPLC

cadena SMILES

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

Clave InChI

YMWUJEATGCHHMB-UHFFFAOYSA-N

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Descripción general

Dichloromethane (DCM) is a chlorinated organic solvent with a wide range of industrial applications. It has C2v symmetry, low boiling point, high density and is immiscible in water. Degradation of DCM by various methods has been reported. Ultrasonic absorption studies of liquid DCM shows strong relaxation effect. A study reports the dielectric characteristics of DCM over a wide frequency range. DCM is susceptible to degradation with time, which can be suppressed by adding amylene as a stabilizer.

Aplicación

Dichloromethane (Methylene chloride) may be used in the following processes:
  • To compose ultrasonic baths for cleaning and protection of aluminum coating over atactic-PMMA (poly(methyl methacrylate)) for dielectric studies.
  • Preparation of AMBF3 (ammoniomethyltrifluoroborate)-conjugated biomolecules.
  • Sample preparation for GC-MS (Gas Chromatography-Mass Spectrometry) analysis.
  • Preparation of ammonium acetate solvent mixture in combination with isopropanol, acetonitrile and water for mass spectral analysis of neutral lipids.
  • Quantification of glutathione (GSH) and glutathione disulfide (GSSG) in biological samples by HPLC and spectrophotometry.
  • As an extractant for 2,2-dithioethyl-4-(2′-pyridyl)-4-butyro-γ-lactone.
Meets ACS specifications

Nota de preparación

Product filtered through a 0.2 μm filter

Pictogramas

Health hazardExclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

does not flash

Punto de inflamabilidad (°C)

does not flash

Equipo de protección personal

Eyeshields, Faceshields, Gloves


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Visite la Librería de documentos

Daniela Giustarini et al.
Nature protocols, 8(9), 1660-1669 (2013-08-10)
This protocol describes a procedure for determining glutathione (GSH) and glutathione disulfide (GSSG) concentrations in blood and other tissues. Artifactual oxidation to GSSG of 5-15% of the GSH found in a sample can occur during deproteination of biological samples with
Rodney C Baker et al.
Methods in enzymology, 538, 89-105 (2014-02-18)
Mass spectrometry technology has enabled significant advances in detailing the alterations of the lipidome in response to pathological conditions or experimental manipulations. Lipids comprise a wide range of compounds with functions that include structural, intracellular signaling, trafficking, and storage. Characterization
Jane A Mullaney et al.
Journal of agricultural and food chemistry, 61(12), 3039-3046 (2013-03-07)
Glucosinolates from the genus Brassica can be converted into bioactive compounds known to induce phase II enzymes, which may decrease the risk of cancers. Conversion via hydrolysis is usually by the brassica enzyme myrosinase, which can be inactivated by cooking
Vitamin B12-mediated hydrodechlorination of dichloromethane by bimetallic Cu/Al particles.
Huang CC, et al.
Chemical Engineering Journal, 273, 413-420 (2015)
Dichloromethane Detection Based on Near-Infrared Absorptive Sensing.
Han JH and Yoon SM
IEEE Journal of Selected Topics in Quantum Electronics, 18(5), 1547-1552 (2012)

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