125431

Cyclohexene

inhibitor-free, ReagentPlus^®, 99%

• Sinónimos: Tetrahydrobenzene
• Fórmula empírica (notación de Hill): C₆H₁₀
• Número de CAS: 110-83-8
• Peso molecular: 82.14
• Beilstein: 906737
• Número CE: 203-807-8
• Número MDL: MFCD00001539
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 57647002
• NACRES: NA.21

Propiedades

• densidad de vapor: 2.8 (vs air)
• Nivel de calidad: 200
• presión de vapor: 160 mmHg ( 20 °C)
• Línea del producto: ReagentPlus^®
• Análisis: 99%
• formulario: liquid
• temp. de autoignición: 590 °F
• lim. expl.: 5 %
• índice de refracción: n20/D 1.446 (lit.)
• bp: 83 °C (lit.)
• mp: −104 °C (lit.)
• solubilidad: water: insoluble
• densidad: 0.811 g/mL at 25 °C (lit.)
• cadena SMILES: C1CCC=CC1
• InChI: 1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
• Clave InChI: HGCIXCUEYOPUTN-UHFFFAOYSA-N

Descripción

Descripción general

Cyclohexene is a cyclic alkene. Kinetics of its reaction with hydrogen in gas and liquid phases over different palladium catalysts supported on silica gel and alumina (temperature range = 264 to 308K and hydrogen pressures = 4 to 89kPa) was investigated. Cyclohexene is formed during the batch-wise partial hydrogenation of benzene over ruthenium catalysts in the presence of an aqueous zinc sulphate solution. Cyclohexene undergoes enantioselective catalytic oxidation in the presence of hydrogen peroxide over environment-friendly peroxytungstate-organic complex catalysts to afford adipic acid. Selective hydrogenation of benzene has been reported to afford cyclohexene. It is an important precursor for the preparation of various chemicals such as cyclohexanol, cyclohexene hydroperoxide, etc.

Aplicación

Cyclohexene has been used to investigate the kinetics of its liquid-phase hydrogenation reaction in the presence of Pd-Al catalyst supported on biomorphic carbon. It may be used for the industrial preparation of cyclohexanol.

Información legal

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• Pictogramas: GHS02,GHS08,GHS07,GHS09
• Palabra de señalización: Danger
• Frases de peligro: H225,H302,H304,H411
• Consejos de prudencia: P210 - P233 - P240 - P273 - P301 + P310 - P331
• Clasificaciones de peligro: Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 2
• Punto de inflamabilidad (°F): 1.4 °F
• Punto de inflamabilidad (°C): -17 °C
• Equipo de protección personal: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter