900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

≥95%

• Sinónimos: 3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate
• Fórmula empírica (notación de Hill): C₃₆H₄₀BF₄N
• Número de CAS: 1810004-87-5
• Peso molecular: 573.51
• Código UNSPSC: 12352005
• NACRES: NA.22

Propiedades

• Nivel de calidad: 100
• Análisis: ≥95%
• formulario: powder or crystals
• idoneidad de la reacción: core: acridinium; reagent type: catalyst; reaction type: Photocatalysis
• mp: 277.2 °C
• activación del fotocatalizador: 455 nm
• cadena SMILES: [F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C
• InChI: InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1
• Clave InChI: YUNSHKYOOCWQRB-UHFFFAOYSA-N

Descripción

Aplicación

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Otras notas

Site-selective arene C-H amination via photoredox catalysis

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable