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Merck
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745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Sinónimos:

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Fórmula empírica (notación de Hill):
C6H14O4S2Zn
Número de CAS:
1416821-55-0
Peso molecular:
279.69
Número MDL:
MFCD24386390
Código UNSPSC:
12352001
ID de la sustancia en PubChem:
329764984
NACRES:
NA.22

Análisis

95%

formulario

solid

idoneidad de la reacción

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

mp

161-166 °C

cadena SMILES

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

Clave InChI

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Aplicación

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Ligadura / enlace

Frequently Asked Questions are available for this Product.

Nota de preparación

may contain up to 1 mole eq ZnCl2

Otras notas

Previously sold under product number L511161

Palabra de señalización

Danger

Frases de peligro

H314,H335,H410

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Yan-Jie Chunyu et al.
Journal of agricultural and food chemistry, 67(31), 8476-8484 (2019-07-13)
Cicada flowers, which are edible and medicinal mushrooms, are the fruiting bodies of Isaria cicadae, a fungus that is parasitic on the larvae of cicada pupae. We hypothesize that host factors might possess stimulatory activity on metabolite synthesis in Isaria
Lucia K Zaugg et al.
Clinical oral implants research, 29(1), 82-90 (2017-10-19)
The purpose of this study was to analyze the cement excess produced when cementing CAD/CAM-fabricated lithium disilicate (L) or zirconium dioxide (Z) crowns using adhesive cement (A) or resin-modified glass ionomer cement (B). Three different cementation techniques were applied: palatal
Xiaopeng Guo et al.
Environmental science and pollution research international, 23(24), 24758-24767 (2016-09-24)
This paper studies the relationship among carbon emissions, GDP, and logistics by using a panel data model and a combination of statistics and econometrics theory. The model is based on the historical data of 10 typical provinces and cities in
Thapanee Srichumpong et al.
Dental materials journal, 38(3), 378-387 (2019-03-15)
The mica-based glass-ceramics were prepared in the SiO2-Al2O3-MgO-MgF2-SrCO3-CaCO3-CaF2-P2O5 glass system. There were four mica-based glass-ceramics produced in this study according to the pigment added (CeO2 or Pr-ZrSiO4/Fe-ZrSiO4) and crystallization time (5-35 min). Four dental glass-ceramics, which were leucite-based, lithium disilicate-based
Young-Hoo Kim et al.
The Journal of arthroplasty, 31(11), 2520-2524 (2016-10-19)
The results of third-generation of alumina-on-alumina ceramic bearing in a large number of patient cohorts are limited. The purpose of this study was to determine clinical and radiologic outcome, prevalence of osteolysis detected with radiographs and computerized tomographic scan, and
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The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

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