520268
4,4′,4″-Tri-tert-Butyl-2,2′:6′,2″-terpyridine
95%
Sinónimos:
2,6-Bis[4-(tert-butyl)pyridin-2-yl)-4-(tert-butyl)pyridine
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About This Item
Fórmula empírica (notación de Hill):
C27H35N3
Número de CAS:
Peso molecular:
401.59
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.22
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Análisis
95%
impurezas
oligomers of tert-butyl-terpyridine
mp
215-217 °C (lit.)
cadena SMILES
CC(C)(C)c1ccnc(c1)-c2cc(cc(n2)-c3cc(ccn3)C(C)(C)C)C(C)(C)C
InChI
1S/C27H35N3/c1-25(2,3)18-10-12-28-21(14-18)23-16-20(27(7,8)9)17-24(30-23)22-15-19(11-13-29-22)26(4,5)6/h10-17H,1-9H3
Clave InChI
QMABMHJGSFUTPF-UHFFFAOYSA-N
Aplicación
4,4′,4-Tri-tert-Butyl-2,2′:6′,2-terpyridine can be used as a ligand:
- In the synthesis of methylated alkanes and ketones via Ni-catalyzed methylation of unactivated alkyl halides and acid chlorides.
- In Ni-catalyzed reductive dimerization reaction.
- In allylic defluorinative reductive cross-coupling reaction in the presence of Ni as a catalyst.
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
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Organic letters, 16(21), 5620-5623 (2014-10-22)
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Michael R Prinsell et al.
Chemical communications (Cambridge, England), 46(31), 5743-5745 (2010-06-29)
The first general method for the reductive dimerization of alkyl halides, alkyl mesylates, alkyl trifluoroacetates, and allylic acetates is reported which proceeds with low catalyst loading (0.5 to 5 mol%), generally high yields (80% ave yield), and good functional-group tolerance.
Cheng-Pan Zhang et al.
Journal of the American Chemical Society, 135(22), 8141-8144 (2013-05-23)
Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this work, we invoked the stabilizing properties of
Gavin D Jones et al.
Journal of the American Chemical Society, 128(40), 13175-13183 (2006-10-05)
The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling reactions. Here, mechanistic studies using isotopically labeled (TMEDA)NiMe(2) (TMEDA = N,N,N',N'-tetramethylethylenediamine) have
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