391638

Dimethylphosphoramidous dichloride

97%

• Sinónimos: (Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride
• Fórmula lineal: (CH₃)₂NPCl₂
• Número de CAS: 683-85-2
• Peso molecular: 145.96
• Número MDL: MFCD00013613
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24864392
• NACRES: NA.22

Propiedades

• Nivel de calidad: 100
• Ensayo: 97%
• Formulario: liquid
• índice de refracción: n20/D 1.505 (lit.)
• bp: 150 °C (lit.)
• densidad: 1.271 g/mL at 25 °C (lit.)
• grupo funcional: amine
• temp. de almacenamiento: 2-8°C
• cadena SMILES: CN(C)P(Cl)Cl
• InChI: 1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
• Clave InChI: XPWWDZRSNFSLRQ-UHFFFAOYSA-N

Descripción

Descripción general

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C₁ symmetry and anti-conformer with C_s symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the ³⁵Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO₂ has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

Aplicación

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:

• N,N-dimethylamidotetrachlorophosphorane
• O-propylchloroformimino-N,N-dimethylamidochlorophosphate
• 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

Información de seguridad

• Pictogramas: GHS02,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H225,H314
• Consejos de prudencia: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Clasificaciones de peligro: Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Riesgos supl.: EUH014
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): -9.4 °F - closed cup
• Punto de inflamabilidad (°C): -23 °C - closed cup
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter