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339121

Sigma-Aldrich

Zirconium(IV) ethoxide

97%

Synonym(s):

Tetraethoxyzirconium, Zirconium ethoxide (Zr(OEt)4 ), Zirconium tetraethoxide

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About This Item

Linear Formula:
Zr(OC2H5)4
CAS Number:
18267-08-8
Molecular Weight:
271.47
MDL number:
MFCD00015654
UNSPSC Code:
12352103
PubChem Substance ID:
24860613
NACRES:
NA.23

Assay

97%

form

solid

reaction suitability

core: zirconium
reagent type: catalyst

bp

235 °C/5 mmHg (lit.)

SMILES string

CCO[Zr](OCC)(OCC)OCC

InChI

1S/4C2H5O.Zr/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4

InChI key

ASBGGHMVAMBCOR-UHFFFAOYSA-N

Related Categories

Application

Convenient precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H228,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6310
MKCN2383
MKCK6847
MKCH4596
MKCB5975

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William J. Evans et al.
Inorganic chemistry, 38(6), 1160-1164 (2001-10-24)
The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three crystallographically characterizable complexes isolable in 55-90% yield are reported. Eugenol, HOC(6)H(3)(OMe-2)(CH(2)CH=CH(2)-4) (HOAr) reacts with [Zr(O(i)Pr)(4)(HO(i)Pr)](2)

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