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911607

Sigma-Aldrich

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

≥95%

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About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4O2P
CAS Number:
2307271-69-6
Molecular Weight:
1069.75
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

photocatalyst activation

465 nm

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Application

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

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Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

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Organic Reaction Toolbox

An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.

Photoredox Catalysis

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.

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