Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

331899

Sigma-Aldrich

(1R,2S)-(−)-2-Amino-1,2-diphenylethanol

99%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
C6H5CH(NH2)CH(C6H5)OH
CAS Number:
23190-16-1
Molecular Weight:
213.28
Beilstein:
2806218
MDL number:
MFCD00074960
UNSPSC Code:
12352116
PubChem Substance ID:
24860006
NACRES:
NA.22

Assay

99%

form

solid

optical activity

[α]25/D −7.0°, c = 0.6 in ethanol

mp

142-144 °C (lit.)

functional group

amine
hydroxyl
phenyl

SMILES string

N[C@H]([C@H](O)c1ccccc1)c2ccccc2

InChI

1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m0/s1

InChI key

GEJJWYZZKKKSEV-UONOGXRCSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Chiral auxiliary used for Pd(II)-assisted chiral tandem alkylation and carbonylative coupling reactions.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCP2851
MKBS5389V
MKBJ5597V
MKBG4279V
MKBD4359

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

J.J. Masters et al.
The Journal of Organic Chemistry, 58, 4547-4547 (1993)
J.J. Masters et al.
The Journal of Organic Chemistry, 56, 5666-5666 (1991)
Michael L Berger et al.
Bioorganic & medicinal chemistry, 17(9), 3456-3462 (2009-04-07)
We resolved 1,2-diphenylethylamine (DPEA) into its (S)- and (R)-enantiomer and used them as precursors for synthesis of (S)- and (R)-1-(1,2-diphenylethyl)piperidine, flexible homeomorphs of the NMDA channel blocker MK-801. We also describe the synthesis of the dicyclohexyl analogues of DPEA. These

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service