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Merck

248649

Sigma-Aldrich

Iodwasserstoffsäure

contains ≤1.5% hypophosphorous acid as stabilizer, ACS reagent, ≥47.0%

Synonym(e):

Hydriotic acid

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About This Item

Empirische Formel (Hill-System):
HI
CAS-Nummer:
Molekulargewicht:
127.91
MDL-Nummer:
UNSPSC-Code:
12352106
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

ACS reagent

Qualitätsniveau

Form

liquid

Enthält

≤1.5% hypophosphorous acid as stabilizer

Konzentration

≥47.0%

bp

127 °C (lit.)

Dichte

1.5 g/mL at 25 °C

Anionenspuren

bromide, chloride (as Cl-): ≤0.05%
sulfate (SO42-): ≤0.005%

Kationenspuren

Fe: ≤0.001%
heavy metals: ≤0.001%

Lagertemp.

2-8°C

SMILES String

I

InChI

1S/HI/h1H

InChIKey

XMBWDFGMSWQBCA-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

Hydriodic acid is a solution of hydrogen iodide in water. It is a strong acid. It is commonly used as a reagent in various reactions such as:
  • electrophilic hydriodination of alkenes and alkynes
  • cleavage of epoxides, ethers, and acetals; conversion of alcohols to iodides   
  • reducing agent for many groups including quinones, α-diketones, α-ketols, α-halo ketones, α-diazo ketones, and sulfoxides      
  • reductive cyclization of keto acids

Hydriodic acid (hypophosphorus acid as a stabilizer) can be used for the fabrication of benzylammonium hybrid layered metal-halide perovskites for spintronic and nonlinear optical applications

Piktogramme

CorrosionEnvironment

Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Nishikata E, et al.
Journal of Chemical and Engineering Data, 26(3), 254-256 (1981)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
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Melanocytes produce two chemically distinct types of melanin pigments, eumelanins and pheomelanins. These pigments can be quantitatively analyzed by acidic KMnO4 oxidation or reductive hydrolysis with hydriodic acid (HI) to form pyrrole-2,3,5-tricarboxylic acid (PTCA) or aminohydroxyphenylalanine (AHP), respectively. Dark brown
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The paper reports on a headspace gas chromatographic (HS-GC) method for the determination of methoxyl in lignin. The method involves the quantitive cleavage of methoxyl with hydroiodic acid (HI) to form methyl iodide in a closed headspace sample vial at

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