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87682

Sigma-Aldrich

Tetramethylorthosilikat

purum, ≥98.0% (GC)

Synonym(e):

Orthokieselsäure-tetramethylester

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About This Item

Lineare Formel:
Si(OCH3)4
CAS-Nummer:
681-84-5
Molekulargewicht:
152.22
Beilstein:
1699658
EG-Nummer:
211-656-4
MDL-Nummer:
MFCD00008341
UNSPSC-Code:
12352103
PubChem Substanz-ID:
329769595
NACRES:
NA.23

Dampfdichte

5.25 (vs air)

Qualitätsniveau

200

Dampfdruck

13 hPa ( 20 °C)

Qualität

purum

Assay

≥98.0% (GC)

Form

liquid

Brechungsindex

n20/D 1.368 (lit.)
n20/D 1.368

bp

121-122 °C (lit.)

mp (Schmelzpunkt)

−4 °C (lit.)

Dichte

1.023 g/mL at 25 °C (lit.)

SMILES String

CO[Si](OC)(OC)OC

InChI

1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3

InChIKey

LFQCEHFDDXELDD-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

Used in the sol-gel synthesis of chromium-doped silicates and in the formation of hexagonal mesoporous silica layers.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

78.8 °F - closed cup

Flammpunkt (°C)

26 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Analysenzertifikate (COA)

Lot/Batch Number
BCCF9753
BCCB0710
BCBZ5464
BCBW8878
BCBW8877

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(3-Aminopropyl)trimethoxysilan 97%

Sigma-Aldrich

281778

(3-Aminopropyl)trimethoxysilan

Yun Tian et al.
Electrophoresis, 29(4), 960-970 (2008-01-24)
A novel calix[4] open-chain crown ether (p-tert-butylcalix[4]arene-1,3-bis(allyloxyethy) ether)-modified, organic-inorganic hybrid silica-based monolithic column possessing vinyl ligands for CEC is described. The monolithic silica matrix containing a vinyl functionality was synthesized by in situ cocondensation of tetramethoxysilane (TMOS) and vinyltrimethoxysilane (VTMS)
Yonghao Xiu et al.
Journal of colloid and interface science, 326(2), 465-470 (2008-07-29)
A method for the preparation of inorganic superhydrophobic silica coatings using sol-gel processing with tetramethoxysilane and isobutyltrimethoxysilane as precursors is described. Incorporation of isobutyltrimethoxysilane into silica layers resulted in the existence of hydrophobic isobutyl surface groups, thereby generating surface hydrophobicity.
Josef Planeta et al.
Journal of chromatography. A, 1217(36), 5737-5740 (2010-08-03)
The temperature effects during the sol-gel process and ageing of the silica-based monolith on the structure and separation efficiency of the capillary columns (100microm i.d., 150mm) for HPLC separations were studied. The tested columns were synthesized from a mixture of
Yan Fang et al.
Journal of chromatography. A, 1217(41), 6405-6412 (2010-09-03)
A simple capillary flow porometer (CFP) was assembled for through-pore structure characterization of monolithic capillary liquid chromatography columns in their original chromatographic forms. Determination of differential pressures and flow rates through dry and wet short capillary segments provided necessary information
Shota Miyazaki et al.
Journal of chromatography. A, 1218(15), 1988-1994 (2010-12-24)
Chromatographic properties of a new type of monolithic silica rod columns were examined. Silica rod columns employed for the study were prepared from tetramethoxysilane, modified with octadecylsilyl moieties, and encased in a stainless-steel protective column with two polymer layers between
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