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D27004

Sigma-Aldrich

N,N′-Diphenylethylendiamin

98%

Synonym(e):

1,2-Dianilino-ethan, N,N′-Ethylendianilin, Wanzlick’s Reagenz für Aldehyde

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About This Item

Lineare Formel:
C6H5NHCH2CH2NHC6H5
CAS-Nummer:
150-61-8
Molekulargewicht:
212.29
Beilstein:
646740
EG-Nummer:
205-765-6
MDL-Nummer:
MFCD00003019
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24893708
NACRES:
NA.22

Assay

98%

Form

powder

mp (Schmelzpunkt)

65-67 °C (lit.)

SMILES String

C(CNc1ccccc1)Nc2ccccc2

InChI

1S/C14H16N2/c1-3-7-13(8-4-1)15-11-12-16-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2

InChIKey

NOUUUQMKVOUUNR-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

N,N′-Diphenylethylenediamine can be used:
  • To prepare nickel(II) chelates to study their chemical reactivities.
  • To prepare N-heterocyclic carbene (NHC) adducts by reacting with substituted benzaldehydes.
  • As a starting material to prepare substituted cyclic poly(methyl methacrylate)s.

Sonstige Hinweise

Remainder mainly 1,4-diphenylpiperazine

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

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Wen-Juan Wei et al.
Chirality, 22(6), 604-611 (2009-11-10)
L-Dibenzoyl tartaric acid was mono-esterified with benzyl alcohol, and then chlorinated with SOCl(2) to give (2S,3S)-1-(benzyloxy)-4-chloro-1,4-dioxobutane-2,3-diyl dibenzoate (Selector 1). (1R,2R)-1,2-Diphenylethylenediamine was mono-functionalized with phenyl isocyanate and phenylene diisocyanate in sequence to give (1R,2R)-1,2-diphenyl-2-(3-phenylureido)ethyl 4- isocyanatophenylurea (Selector 2). Two brush-type chiral
M Noji et al.
Chemico-biological interactions, 51(1), 37-48 (1984-09-01)
A series of Pt(II) complexes containing 1,2-diphenylethylenediamine (stien) isomers were synthesized and tested for their antitumor activity against leukemia L1210. Among the Pt(II) complexes examined water-soluble Pt(II) complexes with sulfate, nitrate and D-glucuronate ions as leaving groups exhibited relatively high
Yoshitane Imai et al.
Organic letters, 10(3), 469-471 (2008-01-11)
In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1'-binaphthyl-2,2'-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules: (1R,2R)-1, (1S,2S)-1, (R)-2, and (S)-2.
Determination of plasma catecholamines via condensation with diphenylethylenediamine: simplification of the procedure.
P Husek et al.
Journal of chromatography, 533, 166-170 (1990-11-30)
Yangzhou Li et al.
Organic & biomolecular chemistry, 3(14), 2513-2518 (2005-07-07)
Polymer-supported chiral ligands 9 and 17 were prepared based on Noyori's (1S,2S)- or (1R,2R)-N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine. The combination with [RuCl2(p-cymene)]2 has been shown to exhibit high activities and enantioselectivities for heterogeneous asymmetric transfer hydrogenation of aromatic ketones (19a-c) with formic acid-triethylamine azeotrope
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