ALD00006

Sodium bis(2-hydroxy-2-methylbutyrato)oxochromate(V)

• Synonym(e): 2-Hydroxy-2-methyl-butanoic acid chromium complex
• Empirische Formel (Hill-System): C₁₀H₁₆CrNaO₇
• CAS-Nummer: 66767-36-0
• Molekulargewicht: 323.22
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329772512
• NACRES: NA.22

Eigenschaften

• Form: solid
• mp (Schmelzpunkt): 340-350 °C
• SMILES String: [O-][Cr]1(O2)(OC(C(C)(CC)O1)=O)OC(C)(CC)C2=O.[Na+]
• InChI: 1S/2C5H9O3.Cr.Na.O/c2*1-3-5(2,8)4(6)7;;;/h2*3H2,1-2H3,(H,6,7);;;/q2*-1;+4;+1;-1/p-2
• InChIKey: NIZKSTMLMALTGU-UHFFFAOYSA-L

Beschreibung

Anwendung

Oxidant was reported by the Baran group to promote selective allylic oxidation of a synthetic intermediate derived from (+)-taxadiene en route to the synthesis of (−)-taxyunnanine D.

Two-Phase Synthesis of (−)-Taxuyunnanine D

Sicherheitshinweise

• Piktogramme: GHS03
• Signalwort: Danger
• H-Sätze: H272
• P-Sätze: P220
• Gefahreneinstufungen: Ox. Sol. 2
• Lagerklassenschlüssel: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable