Alle Fotos(2)
Wichtige Dokumente
792594
3,6-Dichloro-1,2,4,5-tetrazine
96%
Synonym(e):
Dichloro-s-tetrazine
Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(2)
About This Item
Empirische Formel (Hill-System):
C2Cl2N4
Molekulargewicht:
150.95
MDL-Nummer:
UNSPSC-Code:
12352200
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
96%
Form
solid
Verfügbarkeit
available only in USA
mp (Schmelzpunkt)
146-151 °C
Lagertemp.
2-8°C
SMILES String
ClC1=NN=C(Cl)N=N1
InChI
1S/C2Cl2N4/c3-1-5-7-2(4)8-6-1
InChIKey
HXXFMIAFWKZHDY-UHFFFAOYSA-N
Anwendung
Reagent has been reported in stapling of complex peptides as a photochemical trigger. Professor Amos Smith and coworkers have displayed this application in several recent reports.
Sonstige Hinweise
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Oral - Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Mohannad Abdo et al.
Organic letters, 14(13), 3518-3521 (2012-06-27)
The design, solid-phase synthesis, and photochemical validation of diverse peptide linchpins, containing the S,S-tetrazine phototrigger, have been achieved. Steady state irradiation or femtosecond laser pulses confirm their rapid photofragmentation. Attachment of peptides to the C- and N-termini will provide access
Joel R Courter et al.
The Journal of organic chemistry, 79(2), 759-768 (2013-12-24)
The design and synthesis of alanine-rich α-helical peptides constrained in a partially unfolded state by incorporation of the S,S-tetrazine phototrigger has been achieved, permitting, upon photochemical release, observation by 2D-IR spectroscopy of the subnanosecond conformational dynamics that govern the early
Stephen P Brown et al.
Journal of the American Chemical Society, 137(12), 4034-4037 (2015-03-21)
Protocols have been achieved that permit facile introduction of s-tetrazine into unprotected peptides and the protein, thioredoxin, between two cysteine sulfhydryl groups (i.e., staple), followed by photochemical release (i.e., unstaple) and regeneration of the peptide/protein upon removal of the cyano
Tetrazine phototriggers: probes for peptide dynamics.
Matthew J Tucker et al.
Angewandte Chemie (International ed. in English), 49(21), 3612-3616 (2010-04-15)
Matthew J Tucker et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(43), 17314-17319 (2013-10-10)
The relaxation of helical structures very close to equilibrium is observed via transient 2D IR spectroscopy. An initial distribution of synthetically distorted helices having an unnatural bridge linking the 10th and 12th residues of an alanine-rich α-helix is released to
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