752959

(Tributylphosphoranylidene)acetonitrile solution

1 M in toluene

• Synonym(e): CMBP solution, Tsunoda reagent, Cyanomethylene)tributylphosphorane
• Empirische Formel (Hill-System): C₁₄H₂₈NP
• Molekulargewicht: 241.35
• MDL-Nummer: MFCD01321151
• UNSPSC-Code: 12352001
• PubChem Substanz-ID: 329766327
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 100
• Konzentration: 1 M in toluene
• Brechungsindex: n/D 1.500 (lit.); n20/D 1.501
• Dichte: 0.886 g/mL at 25 °C
• Funktionelle Gruppe: nitrile; phosphine
• Lagertemp.: 2-8°C
• SMILES String: CCCCP(CCCC)(CCCC)=CC#N
• InChI: 1S/C14H28NP/c1-4-7-11-16(14-10-15,12-8-5-2)13-9-6-3/h14H,4-9,11-13H2,1-3H3
• InChIKey: OZMLUMPWPFZWTP-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

(Tributylphosphoranylidene)acetonitrile is a stabilized trialkylphosphorane that can act as a substitute to the diethyl azodicarboxylate and triphenylphosphine (DEAD-TPP) system for Mitsunobu reaction between nucleophiles (HA) and alcohols (ROH) to form RA. It is highly useful when the pKa of the nucleophiles are higher than 11.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H225,H304,H315,H336,H361d,H373,H412
• P-Sätze: P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313
• Gefahreneinstufungen: Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• Zielorgane: Central nervous system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 44.6 °F - closed cup
• Flammpunkt (°C): 7 °C - closed cup