710385

Bis(3,5-dimethyl-4-methoxyphenyl)chlorphosphin

95%

• Empirische Formel (Hill-System): C₁₈H₂₂ClO₂P
• CAS-Nummer: 136802-85-2
• Molekulargewicht: 336.79
• MDL-Nummer: MFCD01630810
• UNSPSC-Code: 12352112
• PubChem Substanz-ID: 329762920
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 95%
• Form: liquid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• Brechungsindex: n20/D 1.597
• Dichte: 1.141 g/cm³ at 25 °C
• Funktionelle Gruppe: phosphine
• SMILES String: COc1c(C)cc(cc1C)P(Cl)c2cc(C)c(OC)c(C)c2
• InChI: 1S/C18H22ClO2P/c1-11-7-15(8-12(2)17(11)20-5)22(19)16-9-13(3)18(21-6)14(4)10-16/h7-10H,1-6H3
• InChIKey: JWCZKGYRAINWJA-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Asymmetric organocatalytic electrophilic phosphination
• Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands
• Synthesis of ferrocene-based chiral diphosphines
• Alcoholysis of phosphane-boranes
• Asymmetric hydrogenations of bifep-type biferrocenes

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P280 - P305 + P351 + P338 - P310
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable