594539
4-Methoxycarbonylphenylborsäure
≥95%
Synonym(e):
Methyl-4-boron-benzoat
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Alle Fotos(3)
About This Item
Empirische Formel (Hill-System):
C8H9BO4
CAS-Nummer:
Molekulargewicht:
179.97
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
≥95%
Form
powder
mp (Schmelzpunkt)
197-200 °C (lit.)
SMILES String
COC(=O)c1ccc(cc1)B(O)O
InChI
1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3
InChIKey
PQCXFUXRTRESBD-UHFFFAOYSA-N
Verwandte Kategorien
Anwendung
Reagent used for
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
- Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides
- One-pot ipso-nitration of arylboronic acids
- Copper-catalyzed nitration
- Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling
- Reagent used in Preparation of
- Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid†
- Chromenones and their bradykinin B1 antagonistic activit†
- Pt nanoparticles@Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injectio†
- Salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor†
Sonstige Hinweise
Contains varying amount of anhydride
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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alpha-Amino acid thiol esters derived from N-protected mono-, di-, and tripeptides couple with aryl, pi-electron-rich heteroaryl, or alkenyl boronic acids in the presence of stoichiometric Cu(I) thiophene-2-carboxylate and catalytic Pd(2)(dba)(3)/triethylphosphite to generate the corresponding N-protected peptidyl ketones in good-to-excellent yields
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