364975

(Triphenylphosphin)kupferhydridhexamer

90%

• Synonym(e): Hydrid-(triphenylphosphin)-kupfer(I)-hexamer, Kupfer(I)-hydrid-triphenylphosphin Hexamer, Stryker-Reagenz
• Lineare Formel: [(C₆H₅)₃PCuH]₆
• CAS-Nummer: 33636-93-0
• Molekulargewicht: 1961.04
• MDL-Nummer: MFCD00221518
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24862472
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 90%
• Eignung der Reaktion: reagent type: reductant
• Funktionelle Gruppe: phosphine
• SMILES String: [CuH].[CuH].[CuH].[CuH].[CuH].[CuH].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12.c%13ccc(cc%13)P(c%14ccccc%14)c%15ccccc%15.c%16ccc(cc%16)P(c%17ccccc%17)c%18ccccc%18
• InChI: 1S/6C18H15P.6Cu.6H/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;;;;;;;/h6*1-15H;;;;;;;;;;;;
• InChIKey: PYHLOCIDGQNZFY-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Triphenylgermanium hydride is a hydrogen donor.

Anwendung

Useful synthetic applications include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.

Catalyst for:

• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates
• Chemoselective preparation of alcohols via hydrogenation of aldehydes
• 1,2-addition/transmetalation reactions
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins
• Hydrosilylation reactions
• Chiral hydrogenation reactions
• Hydrostannation of activated alkynes

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Warning
• H-Sätze: H228
• P-Sätze: P210 - P240 - P241 - P280 - P370 + P378
• Gefahreneinstufungen: Flam. Sol. 2
• Lagerklassenschlüssel: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves