302937
Perfluor(methylcyclohexan)
technical grade, 90%
Synonym(e):
(Trifluormethyl)-undecafluor-cyclohexan, Perfluormethylcyclohexan
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About This Item
Lineare Formel:
C6F11CF3
CAS-Nummer:
Molekulargewicht:
350.05
Beilstein:
1915981
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualität
technical grade
Qualitätsniveau
Assay
90%
Form
liquid
Brechungsindex
n17/D 1.285 (lit.)
bp
76 °C (lit.)
Dichte
1.787 g/mL at 25 °C (lit.)
Funktionelle Gruppe
fluoro
SMILES String
FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
InChI
1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
InChIKey
QIROQPWSJUXOJC-UHFFFAOYSA-N
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Allgemeine Beschreibung
Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.
Anwendung
Perfluoro(methylcyclohexane) can be used as:
It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
- A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
- A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.
It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves
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