289094

tert-Butyldimethylsilanol

99%

• Synonym(e): 1-(1,1-Dimethylethyl)-1,1-dimethylsilanol, tert-Butyl(hydroxy)dimethylsilane, tert-Butyldimethylsilanol, tert-Butyldimethylsilyl hydroxide, Dimethyl-tert-butylsilanol
• Lineare Formel: (CH₃)₃CSi(CH₃)₂OH
• CAS-Nummer: 18173-64-3
• Molekulargewicht: 132.28
• Beilstein: 1732777
• MDL-Nummer: MFCD00010673
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24857384
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.424 (lit.)
• bp: 139 °C/739 mmHg (lit.)
• Dichte: 0.84 g/mL at 25 °C (lit.)
• SMILES String: CC(C)(C)[Si](C)(C)O
• InChI: 1S/C6H16OSi/c1-6(2,3)8(4,5)7/h7H,1-5H3
• InChIKey: FGWRMMTYIZKYMA-UHFFFAOYSA-N

Beschreibung

Anwendung

tert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:

• For the preparation of α-chiral ether derivatives by catalytic asymmetric allylic substitution.
• As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.
• In the synthesis of enol silyl ethers.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226 - H315 - H319 - H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 113.0 °F - closed cup
• Flammpunkt (°C): 45 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter