144819

1-(Trimethylsiloxy)cyclohexen

99%

• Synonym(e): 1-Cyclohexenyloxy-trimethylsilan, Cyclohexanonenol-trimethylsilylether
• Lineare Formel: C₆H₉OSi(CH₃)₃
• CAS-Nummer: 6651-36-1
• Molekulargewicht: 170.32
• Beilstein: 1859394
• EG-Nummer: 229-675-1
• MDL-Nummer: MFCD00001541
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24848686
• NACRES: NA.22

Eigenschaften

• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.447 (lit.)
• bp: 64-65 °C/15 mmHg (lit.)
• Dichte: 0.875 g/mL at 25 °C (lit.)
• SMILES String: C[Si](C)(C)OC1=CCCCC1
• InChI: 1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
• InChIKey: SBEMOANGDSSPJY-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).

Anwendung

1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ^1,9- octalone. It is intermediate to many complex compounds including natural products.

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Warning
• H-Sätze: H226
• Gefahreneinstufungen: Flam. Liq. 3
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 105.8 °F - closed cup
• Flammpunkt (°C): 41 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter