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Key Documents

32824

Supelco

Fluazifop

PESTANAL®, analytical standard

Sinonimo/i:

2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid

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About This Item

Formula empirica (notazione di Hill):
C15H12F3NO4
Numero CAS:
Peso molecolare:
327.26
Beilstein:
552236
Numero MDL:
Codice UNSPSC:
41116107
ID PubChem:
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

Nome Commerciale

PESTANAL®

Durata

limited shelf life, expiry date on the label

tecniche

HPLC: suitable
gas chromatography (GC): suitable

applicazioni

agriculture
environmental

Formato

neat

Stringa SMILE

CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O

InChI

1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)
YUVKUEAFAVKILW-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.

Applicazioni

Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
  • Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
  • Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Prodotti consigliati

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Note legali

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Health hazardEnvironment

Avvertenze

Warning

Indicazioni di pericolo

Consigli di prudenza

Classi di pericolo

Aquatic Acute 1 - Repr. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Certificati d'analisi (COA)

Lot/Batch Number

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K A Walker et al.
The Biochemical journal, 254(3), 811-817 (1988-09-15)
Concentrations of fluazifop-butyl sprayed on intact plants caused large decreases in the incorporation of radioactivity from [1-14C]acetate into lipids of barley (Hordeum vulgare) leaves and stems, but did not affect leaves or stems of pea (Pisum sativum). Labelling of all
J Hajslová et al.
Journal of chromatography, 438(1), 55-60 (1988-04-01)
Fluazifop-butyl, haloxyfop-ethoxyethyl and quizalofop-ethyl, active ingredients of new selective herbicidal preparations, as well as their metabolites converted in to corresponding methyl esters were separated on several gas chromatographic columns. Bromination of fluazifop esters increased significantly the response of the electron-capture
Ahmed A Tantawy
Journal of the Egyptian Society of Parasitology, 32(3), 837-847 (2003-01-07)
The herbicides, Butachlor and Fluazifop-p-butyl were evaluated against B. alexandrina and their infection with S. mansoni, as well as against the miracidia and cercariae. The tested herbicides reduced the survival and infection rates of B. alexandrina by 28% and 35.71%
Validation and uncertainty study of a comprehensive list of 160 pesticide residues in multi-class vegetables by liquid chromatography-tandem mass spectrometry.
Kmellar B, et al.
Journal of Chromatography A, 1215(1-2), 37-50 (2008)
E Bolygo et al.
Fresenius' journal of analytical chemistry, 368(8), 816-819 (2001-03-03)
An LC-MS-MS assay is described for fluazifop residue analysis in crops. The residues are extracted with acidified organic solvent, the esters and conjugates are hydrolysed with 6 M hydrochloric acid, then the extracts are cleaned-up by solid phase extraction using

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