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Documenti fondamentali

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Supelco

Tembotrione

PESTANAL®, analytical standard

Sinonimo/i:

2-{2-Chloro-4-(methylsulfonyl)-3-[(2,2,2-trifluoroethoxy)methyl]benzoyl}-1,3-cyclohexanedione, 2-{2-Chloro-4-mesyl-3-[(2,2,2-trifluoroethoxy)methyl]benzoyl}cyclohexane-1,3-dione

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About This Item

Formula empirica (notazione di Hill):
C17H16ClF3O6S
Numero CAS:
Peso molecolare:
440.82
Numero MDL:
Codice UNSPSC:
41116107
ID PubChem:
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

Nome Commerciale

PESTANAL®

Durata

limited shelf life, expiry date on the label

tecniche

HPLC: suitable
gas chromatography (GC): suitable

applicazioni

agriculture
environmental

Formato

neat

Stringa SMILE

CS(=O)(=O)c1ccc(c(Cl)c1COCC(F)(F)F)C(=O)C2C(=O)CCCC2=O

InChI

1S/C17H16ClF3O6S/c1-28(25,26)13-6-5-9(15(18)10(13)7-27-8-17(19,20)21)16(24)14-11(22)3-2-4-12(14)23/h5-6,14H,2-4,7-8H2,1H3
IUQAXCIUEPFPSF-UHFFFAOYSA-N

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Descrizione generale

Tembotrione is a member of β-triketone family of herbicides that is utilized for grass and broadleaf weed control during early to mid-post-emergence of field corn.

Applicazioni

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tembotrione may be used as a reference standard for the determination of tembotrione in tomato by quick, easy, cheap, effective, rugged and safe (QuEchERS) extraction method and dispersive liquid-liquid microextraction (DLLME) followed by analysis using high performance liquid chromatography (HPLC) with diode array detection (DAD), in honeybees by modified QuEchERS extraction followed by analysis using LC and gas chromatography (GC) combined with tandem mass spectrometry (MS/MS), in food samples by ultra-high performance liquid chromatography (UHPLC) and quadrupole time-of-flight mass spectrometry (QTOFMS) with electrospray ionization and in plant tissues as well as water samples by DLLME, matrix solid-phase dispersion (MSPD), and solid-phase extraction (SPE) combined with HPLC-DAD.

Note legali

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1 - STOT RE 2

Organi bersaglio

Eyes,Liver,Kidney

Codice della classe di stoccaggio

13 - Non Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

No data available

Punto d’infiammabilità (°C)

No data available

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Certificati d'analisi (COA)

Lot/Batch Number

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Screening of over 600 pesticides, veterinary drugs, food-packaging contaminants, mycotoxins, and other chemicals in food by ultra-high performance liquid chromatography quadrupole time-of-flight mass spectrometry (UHPLC-QTOFMS).
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Food Analytical Methods, 10(5), 1216-1244 (2017)
Extraction procedures for the study of phytotoxicity and degradation processes of selected triketones in a water ecosystem.
Barchanska H, et al.
Environmental Science and Pollution Research International, 21(6), 4751-4758 (2014)
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Pest management science, 74(10), 2325-2334 (2017-11-07)
Resistance to the 4-hydroxyphenylpyruvate dioxygenase (HPPD)-inhibiting herbicide tembotrione in an Amaranthus palmeri population from Nebraska (NER) has previously been confirmed to be attributable to enhanced metabolism. The objective of this study was to identify and quantify the metabolites formed in
Analysis of pesticides in tomato combining QuEChERS and dispersive liquid-liquid microextraction followed by high-performance liquid chromatography.
Melo A, et al.
Food Analytical Methods, 6(2), 559-568 (2013)
Monopersulfate photocatalysis under 365 nm radiation. Direct oxidation and monopersulfate promoted photocatalysis of the herbicide tembotrione.
Solis RR, et al.
Journal of Environmental Management, 181, 385-394 (2016)

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