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Documenti fondamentali

15256

Supelco

BSA+TMCS

for GC derivatization, LiChropur, 93.0-97.0% (GC)

Sinonimo/i:

Bis(trimethylsilyl)acetamide + Trimethylchlorosilane

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About This Item

Codice UNSPSC:
41116105
ID PubChem:
NACRES:
NA.22

Grado

for GC derivatization

Livello qualitativo

Saggio

93.0-97.0% (GC)

Qualità

LiChropur

Composizione

trimethylchlorosilane (minor component), 3.0-5.0% GC

Impiego in reazioni chimiche

reagent type: derivatization reagent
reaction type: Silylations

tecniche

gas chromatography (GC): suitable

Descrizione generale

BSA+TMCS combination, is one of the most commonly used silylating reagents. BSA is readily used for silylating a wide range of functional groups such as non-sterically hindered alcohols, amides, amines, amino acids, carboxylic acids, and enols. TMCS is a silylation catalyst always used with other silylation reagents to increase the reactivity in derivatization of alcohols, alkaloids, amines, biogenic amines, carboxylic acids, phenols, and steroids.

Applicazioni

Learn more in the Product Information
Suitable for the derivatization of α-ketoacids, amines, amino acids, cycloserine, histamine and metabolites, phenylethylamines, phosphatidylserines and tryptamines. BSA+TMCS may be used as a derivatizing reagent for the determination of steryl glycosides in biodiesel using gas chromatography–mass spectrometry.
Suitable for the derivatization of a-ketoacids, amines, amino acids, cycloserine, histamine and metabolites, phenylethylamines, phosphatidylserines and tryptamines.

Caratteristiche e vantaggi

  • BSA+TMCS has good solvent properties and can function as a silylation reagent without additional solvents.        
  • Alternatively, the mixture is very soluble in most commonly used silylation solvents.        
  • This combination is extremely sensitive to moisture and should be handled under dry conditions.

Altre note

Powerful silylation mixture with wide applicability
Reagent for trimethylsilyl diglyceride, trimethylsilyl (TMS) and trimethylsilyl oximes.

Note legali

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Prodotti correlati

N° Catalogo
Descrizione
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Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1A

Rischi supp

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

53.6 °F - closed cup

Punto d’infiammabilità (°C)

12 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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P. Englmaier
Z. Anal. Chem., 324, 338-338 (1986)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
Ashwin Unnikrishnan et al.
Nucleic acids research, 44(22), 10644-10661 (2016-09-09)
Aberrant stem cell-like gene regulatory networks are a feature of leukaemogenesis. The ETS-related gene (ERG), an important regulator of normal haematopoiesis, is also highly expressed in T-ALL and acute myeloid leukaemia (AML). However, the transcriptional regulation of ERG in leukaemic
D.R. Knapp
Handbook of Analytical Derivatization Reactions, 202-202 (1979)
D.L. Sondack et al.
Journal of Pharmacological Sciences, 62, 1344-1344 (1973)

Articoli

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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