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Key Documents

02578

Supelco

(±)-Epichlorohydrin

analytical standard

Sinonimo/i:

(±)-2-(Chloromethyl)oxirane, 1-Chloro-2,3-epoxypropane

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About This Item

Formula empirica (notazione di Hill):
C3H5ClO
Numero CAS:
Peso molecolare:
92.52
Beilstein:
79785
Numero CE:
Numero MDL:
Codice UNSPSC:
41116107
ID PubChem:
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

Densità del vapore

3.2 (vs air)

Tensione di vapore

13.8 mmHg ( 21.1 °C)

Saggio

≥99.9% (GC)

Temp. autoaccensione

779 °F

Durata

limited shelf life, expiry date on the label

Limite di esplosione

21 %

tecniche

HPLC: suitable
gas chromatography (GC): suitable

Indice di rifrazione

n20/D 1.438 (lit.)
n20/D 1.438

P. eboll.

115-117 °C (lit.)

Punto di fusione

−57 °C (lit.)

Densità

1.183 g/mL at 25 °C (lit.)

applicazioni

cleaning products
cosmetics
environmental
food and beverages
personal care

Formato

neat

Stringa SMILE

ClCC1CO1

InChI

1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2
BRLQWZUYTZBJKN-UHFFFAOYSA-N

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Descrizione generale

Epichlorohydrin (ECH) is a colorless, volatile and highly reactive organic compound which is utilized as a precursor in the production of glycerol, plastics, drugs and paints.
This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food. Find all available reference materials for compounds listed in 10/2011 here

Applicazioni

ECH has been used as a reference standard for the identification of ECH in epoxy-coated cans by oxolane derivatization and gas chromatography−mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode and in drinking water by static headspace (HS) and purge and trap (P&T) coupled to GC equipped with an electron capture detector (GC-ECD).
It may be used as a reference standard for the analysis of (±)-ECH in drinking water by ion chromatography and in effluent water from wastewater treatment plants by HS-solid phase microextraction (HS-SPME) combined with GC-flame ionization detector (GC-FID) and GC-ECD.

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

82.4 °F

Punto d’infiammabilità (°C)

28 °C

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Determination of epichlorohydrin by ion chromatography.
Sarzanini, et al.
Journal of Chromatography A, 884(1-2), 251-259 (2000)
Static headspace and purge-and-trap gas chromatography for epichlorohydrin determination in drinking water.
Lucentini, et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 80(1), 89-98 (2005)
A convenient method for epichlorohydrin determination in water using headspace-solid-phase microextraction and gas chromatography.
Lasa, et al.
Journal of Chromatographic Science, 44(7), 438-443 (2006)
New method for determination of epichlorohydrin in epoxy-coated cans by oxolane derivatization and gas chromatography-mass spectrometry.
Sung, et al.
Journal of Chromatography A, 1201(1), 100-105 (2008)
A K Giri
Mutation research, 386(1), 25-38 (1997-03-01)
Epichlorohydrin (ECH) is one of the more commercially important aliphatic epoxides used extensively as an industrial intermediate, a laboratory reagent, and as an insecticide. It is a volatile, colourless liquid with an ethereal odour. It behaves as an alkylating agent.

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