A88476

4-Methoxybenzoyl chloride

99%

• Sinonimo/i: 4-Anisoyl chloride, p-Anisoyl chloride
• Formula condensata: CH₃OC₆H₄COCl
• Numero CAS: 100-07-2
• Peso molecolare: 170.59
• Beilstein: 471918
• Numero CE: 202-816-4
• Numero MDL: MFCD00000687
• Codice UNSPSC: 12352100
• ID PubChem: 24891375
• NACRES: NA.22

Proprietà

• Livello qualitativo: 200
• Saggio: 99%
• Stato: liquid
• Indice di rifrazione: n20/D 1.581 (lit.)
• P. ebollizione: 262-263 °C (lit.)
• Punto di fusione: 22 °C (lit.)
• Densità: 1.260 g/mL at 20 °C (lit.)
• Stringa SMILE: COc1ccc(cc1)C(Cl)=O
• InChI: 1S/C8H7ClO2/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3; MXMOTZIXVICDSD-UHFFFAOYSA-N

Descrizione

Descrizione generale

4-Methoxybenzoyl chloride is one of the reactive acylating agents that can react with carboxylic acids, alcohols and amines to yield respective carboxylic anhydrides, esters and amides.

4-methoxybenzoyl chloride reacts with potassium thiocyanate to yield isothiocyanate derivative via nucleophilic addition-elimination mechanism.

Applicazioni

• 4-Methoxybenzoyl chloride can be used as radical precursor in visible-light photocatalysis to synthesize various heterocyclic compounds.
• It can be used to synthesize acylphosphine ligands for the rhodium-catalyzed hydrosilylation of alkenes.
• Incorporation of 4-methoxybenzoyl chloride modified indium tin oxide (ITO) as cathode for the fabrication of organic light-emitting diodes (OLEDs) has been reported.
• 1,3 diketones synthesized from 4-methoxybenzoyl chloride can be used in one pot synthesis of various pyrazole derivatives.
• It can also be used in the total synthesis of bioactive compounds like echinoside A and salinosporamide A.

Informazioni sulla sicurezza

• Pittogrammi: GHS05
• Avvertenze: Danger
• Indicazioni di pericolo: H314
• Consigli di prudenza: P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Classi di pericolo: Eye Dam. 1 - Skin Corr. 1B
• Rischi supp: EUH014
• Codice della classe di stoccaggio: 8A - Combustible corrosive hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 1
• Punto d’infiammabilità (°F): 188.6 °F - closed cup
• Punto d’infiammabilità (°C): 87 °C - closed cup
• Dispositivi di protezione individuale: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter