930059

S-Phenyl methanethioate

• Sinonimo/i: Phenyl thioCORMate, Phenyl thioformate
• Formula empirica (notazione di Hill): C₇H₆OS
• Numero CAS: 27064-03-5
• Peso molecolare: 138.19
• Numero MDL: MFCD32756471
• Codice UNSPSC: 12352101
• NACRES: NA.06

Proprietà

• Stato: liquid
• Livello qualitativo: 100
• Indice di rifrazione: n/D 1.586
• Densità: 1.134 g/mL
• Gruppo funzionale: thioether
• Temperatura di conservazione: −20°C
• Stringa SMILE: [H]C(SC1=CC=CC=C1)=O
• InChI: 1S/C7H6OS/c8-6-9-7-4-2-1-3-5-7/h1-6H; ITJOOMDVHPTIRB-UHFFFAOYSA-N

Descrizione

Applicazioni

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315,H319,H335
• Consigli di prudenza: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 10 - Combustible liquids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): 221.0 °F
• Punto d’infiammabilità (°C): 105 °C