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735973

N,N′-Dimethyl N,N′-di(4-pyridinyl)thiuram disulfide

Name: N,N′-Dimethyl N,N′-di(4-pyridinyl)thiuram disulfide
Brand: ALDRICH

Sinonimo/i:

Bis[methyl-(4-pyridinyl)thiocarbamoyl] disulfide, Bis[methyl-(4-pyridinyl)thiocarbamyl] disulfide

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About This Item

Formula empirica (notazione di Hill):

C₁₄H₁₄N₄S₄

Numero CAS:

1158958-94-1

Peso molecolare:

366.55

Numero MDL:

MFCD19687019

Codice UNSPSC:

12352100

ID PubChem:

329765072

NACRES:

NA.23

Prodotti consigliati

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Sigma-Aldrich

718394

6-Chloro-2,4-diamino-1,3,5-triazine-¹³C₃

Forma fisica

solid

Livello qualitativo

100

Punto di fusione

118-128 °C

Stringa SMILE

CN(C(=S)SSC(=S)N(C)c1ccncc1)c2ccncc2

InChI

1S/C14H14N4S4/c1-17(11-3-7-15-8-4-11)13(19)21-22-14(20)18(2)12-5-9-16-10-6-12/h3-10H,1-2H3
PVZGPMRTEJHLMS-UHFFFAOYSA-N

Categorie correlate

Ausili per la polimerizzazione

Materiali biomedicali

Descrizione generale

Precursor for the synthesis of novel switchable RAFT agents for controlled radical polymerization. Chain Transfer Agent (CTA)

Pittogrammi

GHS07

Avvertenze

Warning

Indicazioni di pericolo

H302

Classi di pericolo

Acute Tox. 4 Oral

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

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Sigma-Aldrich

723002

Cyanomethyl methyl(phenyl)carbamodithioate

RAFT Agent Design and Synthesis

Keddie, D. J.; et al.

Macromolecules, 45, 5321-5342 (2012)

Universal (switchable) RAFT agents.

Massimo Benaglia et al.

Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)

The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articoli

Universal (Switchable) RAFT Agents for Well-Defined Block Copolymers

Universal (Switchable) RAFT agents allow for the polymerization of both less activated and more activated monomers and are ideal for the synthesis of well-defined block copolymers.

Evaluation of RAFT Agents

A series of polymerization were carried out using RAFT agents and monomers yielding well-defined polymers with narrow molecular weight distributions.

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Tools for Performing ATRP

Vedi tutto

Protocolli

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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