701998

[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

98%

• Sinonimo/i: PdCl₂(dcypf)
• Formula empirica (notazione di Hill): C₃₄H₅₂Cl₂FeP₂Pd
• Numero CAS: 917511-90-1
• Peso molecolare: 755.90
• Numero MDL: MFCD11656081
• Codice UNSPSC: 12161600
• ID PubChem: 329762337
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 98%
• Stato: powder
• Impiego in reazioni chimiche: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• Punto di fusione: 294-300 °C
• Temperatura di conservazione: −20°C
• Stringa SMILE: [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
• InChI: 1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2; HRAMBTUEZQOQRK-UHFFFAOYSA-L

Descrizione

Applicazioni

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)