688487
2-Mesityl-2,5,6,7-tetrahydropyrrolo[2,1-c][1,2,4]triazol-4-ium chloride
97%
Sinonimo/i:
Bode Catalyst 3
About This Item
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Livello qualitativo
Saggio
97%
Forma fisica
solid
Impiego in reazioni chimiche
reagent type: catalyst
Punto di fusione
200-205 °C
Stringa SMILE
[Cl-].Cc1cc(C)c(c(C)c1)-[n+]2cn3CCCc3n2
InChI
1S/C14H18N3.ClH/c1-10-7-11(2)14(12(3)8-10)17-9-16-6-4-5-13(16)15-17;/h7-9H,4-6H2,1-3H3;1H/q+1;/p-1
KKBONGWVMVUYPA-UHFFFAOYSA-M
Applicazioni
- Intermolecular hydroacylation of cyclopropenes
- Crossed acyloin condensations
- Domino ring-opening redox amidation Knoevenagel condensation
- Claisen rearrangement
- Lewis acid- and N-heterocyclic carbene-catalyzed cyclocondensation reaction
- Bode catalyst for enantioselective cyclizations
Note legali
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
dust mask type N95 (US), Eyeshields, Gloves
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Articoli
Rovis has demonstrated that triazolium salt in the presence of a base can act as an N-heterocyclic carbene organocatalyst1 in highly enantioselective intramolecular Stetter reactions.
Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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