682322

(R)-N-Diphenylphosphino-N-methyl-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine

≥96%

• Sinonimo/i: (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, (R)-Methyl-BoPhoz
• Formula empirica (notazione di Hill): C₃₇H₃₅FeNP₂
• Numero CAS: 406680-94-2
• Peso molecolare: 611.47
• Numero MDL: MFCD05865220
• Codice UNSPSC: 12352005
• ID PubChem: 329760488
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: ≥96%
• Stato: solid
• Punto di fusione: 108.7-113.6 °C
• Gruppo funzionale: amine; phosphine
• Stringa SMILE: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
• InChI: 1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1; ZIAZHUWEJYUGEO-FBHGDYMESA-N

Descrizione

Applicazioni

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.

Efficient ligand for asymmetric hydrogenation

Note legali

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable