590231

Di(acetato)dicyclohexylphenylphosphinepalladium(II), polymer-bound FibreCat^®

Pd ~5 %, extent of labeling: 0.4-0.6 mmol/g PPH₃ ligand content loading

• Numero CAS: 480445-43-0
• Numero MDL: MFCD04118909
• Codice UNSPSC: 12352103
• NACRES: NA.22

Proprietà

• Nome Commerciale: FibreCat^®
• Livello qualitativo: 100
• Stato: solid
• Composizione: Pd, ~5%
• Impiego in reazioni chimiche: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reaction type: solution phase peptide synthesis; reagent type: catalyst; reaction type: Coupling Reactions
• Grado di funzionalizzazione: 0.4-0.6 mmol/g PPH₃ ligand content loading
• Stringa SMILE: [Pd+2].P(C3CCCCC3)(C2CCCCC2)c1ccccc1.[O-]C(=O)C.[O-]C(=O)C
• InChI: ZMMYBYFXUHUTSH-UHFFFAOYSA-L

Descrizione

Applicazioni

Supported catalyst used in Suzuki coupling of less reactive aryl chloride with boronic acids. This supported catalyst is generally more selective than the free homogeneous catalyst, and palladium leaching is very low (<2 ppm).

The resin can also be recycled.

Note legali

FibreCat is a registered trademark of Johnson Matthey PLC

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)