567159

1,1′-Bis(phenylphosphinidene)ferrocene

97%

• Sinonimo/i: 1,1′-(Ferrocenediyl)phenylphosphine
• Formula condensata: C₅H₄PC₆H₅C₅H₄Fe
• Numero CAS: 72954-06-4
• Peso molecolare: 292.09
• Numero MDL: MFCD04974069
• Codice UNSPSC: 12352005
• ID PubChem: 24880349
• NACRES: NA.22

Proprietà

• Saggio: 97%
• Forma fisica: solid
• Impiego in reazioni chimiche: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• Punto di fusione: 88-92 °C (lit.)
• Gruppo funzionale: phosphine
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
• InChI: 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;; HKOUDNXXOXEYNZ-UHFFFAOYSA-N

Descrizione

Applicazioni

Reactant for:

• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)