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Key Documents

A7302

Sigma-Aldrich

Ammonium molybdate tetrahydrate

ACS reagent, 81.0-83.0% MoO3 basis

Synonyme(s) :

Ammonium heptamolybdate tetrahydrate, Molybdic acid ammonium salt tetrahydrate

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About This Item

Formule linéaire :
(NH4)6Mo7O24 · 4H2O
Numéro CAS:
Poids moléculaire :
1235.86
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.21

Qualité

ACS reagent

Niveau de qualité

Agence

suitable for SM 5210

Pureté

81.0-83.0% MoO3 basis

Forme

crystalline

Pertinence de la réaction

reagent type: catalyst
core: molybdenum

Impuretés

≤0.005% Insoluble matter

Densité

2.498 g/mL at 25 °C (lit.)

Traces d'anions

arsenate, phosphate, and silicate (as SiO2): ≤0.001%
chloride (Cl-): ≤0.002%
nitrate (NO3-): passes test (limit about 0.003%)
phosphate (PO43-): ≤5 ppm
sulfate (SO42-): ≤0.02%

Traces de cations

Mg: ≤0.005%
heavy metals: ≤0.001% (as lead)

Température de stockage

room temp

Chaîne SMILES 

N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O

InChI

1S/7Mo.6H3N.10H2O.18O/h;;;;;;;6*1H3;10*1H2;;;;;;;;;;;;;;;;;;/q;;;;3*+2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/p-6

Clé InChI

FIXLYHHVMHXSCP-UHFFFAOYSA-H

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Description générale

Ammonium molybdate tetrahydrate (AMT) is a molybdenum salt, often employed in cryo-negative staining that helps to identify particles while preserving the material. As a catalyst, it is used to desulfurize thiophene and its derivatives.

Application

Ammonium molybdate tetrahydrate can be used as:
  • A molybdenum source in the synthesis of sodium molybdate dihydrate (Na2MoO4·2H2O).
  • A molybdenum source in the synthesis of nickel molybdate nanorods (NiMoO4) by co-precipitation method in the presence of nickel benzoate as a nickel source.
  • A precursor in the synthesis of Mn-MoS2 (MMS). MMS is employed in the production of MMS/rGO (reduced graphene oxide) composite that exhibits the highest rhodamine B (RhB) degradation efficiency.
  • A catalyst in the synthesis of PVDF (polyvinylidene fluoride) catalytic microcapsules. PVDF is a heterogeneous catalyst for the selective oxidation of benzyl alcohol to benzaldehyde.

Qualité

May contain darkened ammonium molybdate crystals that are soluble in water.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Suvarna Sounderajan et al.
Journal of hazardous materials, 149(1), 238-242 (2007-09-01)
Arsenic (V) is known to form heteropolyacid with ammonium molybdate in acidic aqueous solutions, which can be quantitatively extracted into certain organic solvents. In the present work, 12-molybdoarsenic acid extracted in butan-1-ol is used for quantification of As (V). Total
Shifeng Cao et al.
International journal of food microbiology, 141(3), 173-176 (2010-07-08)
The potential enhancement of Pichia membranifaciens by ammonium molybdate (NH(4)Mo) to control blue mould caused by Penicillium expansum on peach fruit was investigated. Combining P. membranifaciens at 1x10(8) cell/ml with 1 mM NH(4)Mo provided a more effective control of blue
Sidney Omelon et al.
Electrophoresis, 28(16), 2808-2811 (2007-07-21)
Nonradioactive polyphosphate (poly(P); (PO(3) (-))(n)) species resolved by PAGE can be detected by hydrolytic degradation of the polyphosphates into orthophosphates (P(i)) with a 5 M HCl solution saturated with NaCl, followed by staining the P(i) degradation products in a 1
Bernard Lorber et al.
Micron (Oxford, England : 1993), 39(4), 431-446 (2007-05-01)
The formation of 2D arrays of three small icosahedral RNA viruses with known 3D structures (tomato bushy stunt virus, turnip yellow mosaic virus and bromegrass mosaic virus) has been investigated to determine the role of each component of a negative
Kyung Ho Park et al.
Journal of hazardous materials, 138(2), 311-316 (2006-07-25)
The petroleum refining industry makes extensive use of hydroprocessing catalysts. These catalysts contain environmentally critical and economically valuable metals such as Mo, V, Ni and Co. In the present study, a simple hydrometallurgical processing of spent hydrodesulphurization (HDS) catalyst for

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