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703206

Sigma-Aldrich

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

95% (NMR)

Synonyme(s) :

Greatcell Solar®, N-3 dye

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About This Item

Formule empirique (notation de Hill):
C26H16N6O8RuS2
Numéro CAS:
141460-19-7
Poids moléculaire :
705.64
Numéro MDL:
MFCD11042213
Code UNSPSC :
12352103
ID de substance PubChem :
329762438
Nomenclature NACRES :
NA.23

Niveau de qualité

200

Pureté

95% (NMR)

Forme

powder

Pf

>300 °C

λmax

534, 395, 312 nm (lit.)

Chaîne SMILES 

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

Clé InChI

VMISXESAJBVFNH-UHFFFAOYSA-N

Catégories apparentées

Description générale

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N3 dye) is a ruthenium polypyridyl based complex that can be used as a sensitizer. It is a highly stable polymer in which the photocurrent decreases with an increase in the concentration of N3 dye.

Application

Efficent DSSCs for Direct Conversion of Sunlight to Electricity
N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE).

Informations légales

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315 - H317 - H319 - H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)
Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy
Fabregat-Santiago F, et al.
Solar Energy Materials and Solar Cells, 87(1-4), 117-131 (2005)
Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements
Zaban A, et al.
ChemPhysChem, 4(8), 859-864 (2003)
Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)
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