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345105

Sigma-Aldrich

Ethylmagnesium bromide solution

1.0 M in tert-butyl methyl ether

Synonyme(s) :

Bromoethylmagnesium

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About This Item

Formule linéaire :
CH3CH2MgBr
Numéro CAS:
925-90-6
Poids moléculaire :
133.27
Numéro Beilstein :
3587203
Numéro MDL:
MFCD00000043
Code UNSPSC :
12352103
ID de substance PubChem :
24861294
Nomenclature NACRES :
NA.22

Capacité de réaction

reaction type: Grignard Reaction

Concentration

1.0 M in tert-butyl methyl ether

Densité

0.841 g/mL at 25 °C

Chaîne SMILES 

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

Clé InChI

TWTWFMUQSOFTRN-UHFFFAOYSA-M

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Application


  • Solution Structure and Magnesium Deposition Electrochemistry of Mixing Alkylmagnesium Halide with Magnesium Sulfonyl Amide/Glyme Solution: This research explores the electrochemical behavior of ethylmagnesium bromide in mixed solutions for magnesium deposition applications (Egashira & Hiratsuka, 2016).

  • Ethyl magnesium bromide as an efficient anionic initiator for controlled polymerization of ε-caprolactone: The article investigates the use of ethylmagnesium bromide as an initiator for the controlled polymerization of ε-caprolactone (Malinová & Brožek, 2014).

  • Room temperature electrodeposition of metallic magnesium from ethylmagnesium bromide in tetrahydrofuran and ionic liquid mixtures: This research focuses on the electrodeposition of metallic magnesium using ethylmagnesium bromide in various solvent mixtures (Chen et al., 2015).

Pictogrammes

FlameCorrosion
GHS02,GHS05

Mention d'avertissement

Danger

Mentions de danger

H225,H260,H314

Classification des risques

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

Risques supp

EUH014

Code de la classe de stockage

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

-29.2 °F - closed cup

Point d'éclair (°C)

-34 °C - closed cup

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Certificats d'analyse (COA)

Lot/Batch Number
SHBJ4731
SHBH0047V
SHBG9055V
SHBB0193
S44016

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
F Turon et al.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
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